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What is Thermal Spray


Methods
Molten Metal FlameSpray

Powder Flame Spraying
Wire Flame Spraying
Ceramic Rod Flame Spraying
Detonation Flame Spraying
High Velocity Oxy/Fuel Spraying (HVOF)
Cold Spray
Nontransferred Plasma Arc Spraying
Electric Arc Spraying
RF Plasma Spraying
References
Acknowledgements
 


Thermal spray raw materials by end-use
Identification
Underlayments and bond coats
Build-up and reclamation
Wear resistance
Clearance control coatings
Thermal barrier coatings
Environmental proteching coatings
Electrical conductivity and resistivity
Biomedical coatings
Metal and ceramic matrix composites
Thermal Spray Processes used by Various Industrial Segments
Chart
Thermal Spray Coating Applications According to Industry Served
Chart
Industrial use of Gas Metallic Materials
Chart

 

Wear resistance
Wear is defined as “surface damage involving a progressive loss of material, due to relative motion between it and a contacting surface or substance”.(1) This definition is suited for most industrial applications as it encompasses the principal causes of wear viz. environmental and mechanical forces. Loss in dimensional size due to wear, thereby resulting in the loss of part usefulness is estimated to cost industry billions in repair and/or replacement. Thermal sprayed coatings serve industry by helping to cope with wear problems. The need for wear resistant surfaces occurs across a broad spectrum of industries. It therefore stands to reason that the extensive and broad market for wear resistant coatings accounts for the greatest utilization of thermal spray consumables.

(1)“Thermal Spray Terminology and Company Origins” Published in 2001 by the ASM Thermal Spray Society, Materials Park, Ohio

Mechanical wear is divided into five (5) categories each of which recognizes the mechanisms causing the damage. As noted previously, these are:

· abrasive
· adhesive
· fretting
· erosion
· cavitation

Abrasive wear

There are two (2) recognizable types of abrasive wear – low temperature and high temperature. The dividing line is approximated at about 900°F (482°C) or the maximum service limit for tungsten carbide (WC) coatings. Abrasive wear occurs when hard particles, present between rubbing surfaces, cut and tear material from either or both surfaces. This results in a decrease in surface finish, dimensional tolerances and performance. Any hard particles as dust, sand, oxides, debris, etc. can cause abrasive wear. Typically, they are introduced by an outside source as ingested air, lubricants or the debris resulting from mate face rubbing.

Some frequently used coating materials used to reduce/prevent abrasive type wear are:

Low temperature wear:

· Aluminum bronze alloys
· Aluminum quasicrystal alloys
· Copper-nickel alloys
· Copper-nickel-indium alloys
· NiCrB self fluxing alloys
· NiCrBSi self fluxing alloys
· NiCrB self fluxing alloys+WC blends
· NiCrBSi self fluxing alloys+WC blends
· CoCrB self fluxing alloys
· CoCrBSi self fluxing alloys
· CoCrB self fluxing alloys+WC blends
· CoCrBSi self fluxing alloys+WC blends
· Aluminum oxide
· Chrome oxide
· Triballoy 400
· Triballoy 800
· Tungsten carbide/cobalt composites
· 431 Stainless steel

High temperature wear:

· Aluminum quasicrystal alloys
· Chromium carbide alloys
· Chromium carbide+Nichrome blends
· Triballoy 400
· Triballoy 800
· Coast Metal 64
· Stellite 6
· Stellite 12
· Stellite 31
· Hastelloy X

Adhesive wear

Surfaces that resist adhesive wear are typically bearings that rub and slide over/against a mating surface as a tribological couple. Bearing coatings should be either softer than the mate face or be of equal hardness. Either serves to prevent loss of finish, dimensional tolerance and functional performance. Soft bearings wear in preference to the mating surface and tend to self align. Hard bearings are designed to be more precisely aligned and to accept higher loads.
Consumables for soft bearing coatings include:

· Aluminum bronze alloys
· Copper-nickel alloys
· Copper-nickel-indium alloys
· Tin babbitt alloys
Sprayed hard bearing materials include:

· Triballoy 400
· Triballoy 800
· Various Stellites
· 431 Stainless steel
· Pure molybdenum
· Molybdenum+NiCrB alloy blends
· Aluminum oxide
· Titanium oxide
· Nickel-aluminum-molybdenum alloys and composites

Fretting

Anti-fretting coatings are used at either low temperatures or high temperatures. As previously, the dividing point is the usefulness of tungsten carbides. Anti-fretting coatings must resist repeated loading over prolonged periods of time. Intended loading may be as in an operating cycle or unintended where vibrations set up small amplitudes between surfaces. With either condition repeated loading sets up alternating stress that cause damage.
Thermal spray materials used to resist fretting include:

· 83/17 tungsten carbide/cobalt composites
· Copper-nickel-indium alloys
· Copper-nickel alloys
· Stellite 6
· Stellite 12
· Stellite 31

Erosion

Erosion resistant coatings are also used at low and high temperatures and again tungsten carbide and 900°F (384°C) is the dividing point. Hard particles impacting upon a surface at high velocity causes erosion by dislodging material from it.

Coatings with excellent erosion resistance are:
· 88/12 tungsten carbide/cobalt composites
· NiCrB fused, self fluxing alloys
· NiCrBSi fused, self fluxing alloys

Cavitation

Cavitation resistant surfaces display a dynamic
form of wear exhibited by fluids in the repeated formation and violent collapse of bubbles. This
generates high hydrodynamic stresses that cause deformation and erosion of surfaces in proximity of the collapsing bubbles.

Materials used to resist cavitation include:

· NiCrB self fluxing alloys
· NiCrBSi self fluxing alloys
· NiCrB self fluxing alloys + WC blends
· NiCrBSi self fluxing alloys + WC blends
· CoCrB self fluxing alloys
· CoCrBSi self fluxing alloys
· CoCrB self fluxing alloys + WC blends
· CoCrBSi self fluxing alloys + WC blends
· Aluminum oxide
· Tungsten carbide/cobalt composites
· Stellite 6
· Stellite 12
· Stellite 31

 
 
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