Wear is defined as “surface damage involving a
progressive loss of material, due to relative motion between it
and a contacting surface or substance”.(1) This definition
is suited for most industrial applications as it encompasses the
principal causes of wear viz. environmental and mechanical forces.
Loss in dimensional size due to wear, thereby resulting in the
loss of part usefulness is estimated to cost industry billions
in repair and/or replacement. Thermal sprayed coatings serve industry
by helping to cope with wear problems. The need for wear resistant
surfaces occurs across a broad spectrum of industries. It therefore
stands to reason that the extensive and broad market for wear
resistant coatings accounts for the greatest utilization of thermal
spray consumables.
(1)“Thermal Spray Terminology
and Company Origins” Published in 2001 by the ASM Thermal
Spray Society, Materials Park, Ohio
Mechanical wear is divided into five
(5) categories each of which recognizes the mechanisms causing
the damage. As noted previously, these are:
· abrasive
· adhesive
· fretting
· erosion
· cavitation
Abrasive wear
There are two (2) recognizable types of abrasive
wear – low temperature and high temperature. The dividing
line is approximated at about 900°F (482°C) or the maximum
service limit for tungsten carbide (WC) coatings. Abrasive wear
occurs when hard particles, present between rubbing surfaces,
cut and tear material from either or both surfaces. This results
in a decrease in surface finish, dimensional tolerances and performance.
Any hard particles as dust, sand, oxides, debris, etc. can cause
abrasive wear. Typically, they are introduced by an outside source
as ingested air, lubricants or the debris resulting from mate
face rubbing.
Some frequently used coating materials used
to reduce/prevent abrasive type wear are:
Low temperature wear:
· Aluminum bronze alloys
· Aluminum quasicrystal alloys
· Copper-nickel alloys
· Copper-nickel-indium alloys
· NiCrB self fluxing alloys
· NiCrBSi self fluxing alloys
· NiCrB self fluxing alloys+WC blends
· NiCrBSi self fluxing alloys+WC blends
· CoCrB self fluxing alloys
· CoCrBSi self fluxing alloys
· CoCrB self fluxing alloys+WC blends
· CoCrBSi self fluxing alloys+WC blends
· Aluminum oxide
· Chrome oxide
· Triballoy 400
· Triballoy 800
· Tungsten carbide/cobalt composites
· 431 Stainless steel
High temperature wear:
· Aluminum quasicrystal alloys
· Chromium carbide alloys
· Chromium carbide+Nichrome blends
· Triballoy 400
· Triballoy 800
· Coast Metal 64
· Stellite 6
· Stellite 12
· Stellite 31
· Hastelloy X
Adhesive wear
Surfaces that resist adhesive wear are typically
bearings that rub and slide over/against a mating surface as a
tribological couple. Bearing coatings should be either softer
than the mate face or be of equal hardness. Either serves to prevent
loss of finish, dimensional tolerance and functional performance.
Soft bearings wear in preference to the mating surface and tend
to self align. Hard bearings are designed to be more precisely
aligned and to accept higher loads.
Consumables for soft bearing coatings include:
· Aluminum bronze alloys
· Copper-nickel alloys
· Copper-nickel-indium alloys
· Tin babbitt alloys
Sprayed hard bearing materials include:
· Triballoy 400
· Triballoy 800
· Various Stellites
· 431 Stainless steel
· Pure molybdenum
· Molybdenum+NiCrB alloy blends
· Aluminum oxide
· Titanium oxide
· Nickel-aluminum-molybdenum alloys and composites
Fretting
Anti-fretting coatings are used at either low
temperatures or high temperatures. As previously, the dividing
point is the usefulness of tungsten carbides. Anti-fretting coatings
must resist repeated loading over prolonged periods of time. Intended
loading may be as in an operating cycle or unintended where vibrations
set up small amplitudes between surfaces. With either condition
repeated loading sets up alternating stress that cause damage.
Thermal spray materials used to resist fretting include:
· 83/17 tungsten carbide/cobalt composites
· Copper-nickel-indium alloys
· Copper-nickel alloys
· Stellite 6
· Stellite 12
· Stellite 31
Erosion
Erosion resistant coatings are also used at
low and high temperatures and again tungsten carbide and 900°F
(384°C) is the dividing point. Hard particles impacting upon
a surface at high velocity causes erosion by dislodging material
from it.
Coatings with excellent erosion resistance are:
· 88/12 tungsten carbide/cobalt composites
· NiCrB fused, self fluxing alloys
· NiCrBSi fused, self fluxing alloys
Cavitation
Cavitation resistant surfaces display a dynamic
form of wear exhibited by fluids in the repeated formation and
violent collapse of bubbles. This
generates high hydrodynamic stresses that cause deformation and
erosion of surfaces in proximity of the collapsing bubbles.
Materials used to resist cavitation include:
· NiCrB self fluxing alloys
· NiCrBSi self fluxing alloys
· NiCrB self fluxing alloys + WC blends
· NiCrBSi self fluxing alloys + WC blends
· CoCrB self fluxing alloys
· CoCrBSi self fluxing alloys
· CoCrB self fluxing alloys + WC blends
· CoCrBSi self fluxing alloys + WC blends
· Aluminum oxide
· Tungsten carbide/cobalt composites
· Stellite 6
· Stellite 12
· Stellite 31